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A button cell used in watches functions ...

A button cell used in watches functions as following
`Zn(s) + Ag _2 O(s) + H_2 O(l)`
`2 A g(s) + Zn^(2+) (aq) = 2 OH^- (aq)`
If half cell potentials are
`Zn^(2+) (aq) +2e^- rarr Zn (s) , E^@ =- 0. 76 V`
`Af_2 O(s) +H_2 O (l) +2e^- rarr`
`2Ag(s) + 2OH^- (aq) , E^@ =0. 34 V`.
The cell potential will be .

A

`0.84 V `

B

`1.34 V`

C

`1.10 V `

D

`0.42 V`

Text Solution

Verified by Experts

The correct Answer is:
C

`E_(cell)^(@) = E_("cathode")^(@) - E_("anode")^(@)`
`=0.34 - (-0.76) = 1.10` V
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A button cell used in watched funcations as follwing Zn(s)+Ag_(2)O(s)+H_(2)O(l)hArr2Ag(s)+Zn^(2+)(aq.)+2OH^(-)(aq) If half cell potentials are Zn^(2+)(aq.)+2e^(-) rarr Zn(s), E^(@) = -0.76 V Ag_(2)O(s)+H_(2)O(l)+2e^(-) rarr 2Ag(s)+2OH^(-)(aq.),, E^(@) = 0.34V The cell potential will be

In the button cells widely used in watches and other devices the following reaction takes place: Zn(s) + Ag_(2)O(s) + H_(2)O (l) to Zn^(2+) (aq) + 2Ag(s) + 2OH^(-)(aq) Determine DeltaG^(@) and E^(@) for the reaction Zn(s) to Zn^(2+) + 2e^(-) , E^(@) = 0.76 V Ag_(2)O + H_(2)O + 2e^(-) to 2Ag + 2OH^(-) E^(@) = +0.34 V

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