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A quantity of PCl(5) was heated in a 10 ...

A quantity of `PCl_(5)` was heated in a 10 `dm^(3)` vessel at `250^(@)C` :
`PCl_(5(g))iffPCl_(3(g))+Cl_(2(g))`
At equilibrium, the vessel contains 0.1 mole of `PCl_(5)` and 0.2 mole of `Cl_(2)`. The equilibrium constant of the reaction is

A

`0.04`

B

`0.025`

C

`0.02`

D

`0.05`

Text Solution

Verified by Experts

The correct Answer is:
A

`{:(,PCl_(5),iff,PCl_(3),+,Cl_(2)),("Moles at eqm.","0.1 mole",,"0.2 mole",,"0.2 mole"),("Molar concs.","0.1/10",,"0.2/10",,"0.2/10"):}`
`K=(0.02xx0.02)/(0.01)=0.04`
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