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Which of the following will show a negat...

Which of the following will show a negative deviation from Raoult's law?

A

Acetone-benzene

B

Acetone-ethanol

C

Benzene-methanol

D

Acetone-chloroform

Text Solution

Verified by Experts

The correct Answer is:
D
Hydrogen bonds are formed on mixing acetone and chloroform. The new interactions in the mixture are stronger than in the pure components. `Delta V` and `DeltaH` are negative. The solution shows negative deviation.
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