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Lowering of vapour pressure in 1 motal a...

Lowering of vapour pressure in 1 motal aqueous solution at `100^@C` is

A

13.44 mm Hg

B

14.12 mm Hg

C

31.2 mm Hg

D

35.2 mm Hg

Text Solution

Verified by Experts

The correct Answer is:
A

Molality and mole fraction are related as follows :
`m = (x_B xx 1000)/((1-x_B)m_A), 1 = (x_B xx 1000)/((1-x_B) xx 18)`
`x_B` = mole fraction of solute, `m_A` = molar mass of solvent
`x_B` = 0.0176, `x_A` = 0.9824, p=p `x_A`
`=p 760 xx 0.9824=746.624 , Delta p = p-p= 760 -746.624`
`~~` 13.4 mm Hg
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