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Define standard emf of a cell....

Define standard emf of a cell.

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Given the standard half - cell potentials (E^(@)) of the following as : Zn rarr Zn^(2+)+2e , E^(@)=+0.76V Fe rarr Fe^(2+)+2e, E^(@)=0.41V The the standard EMF of the cell with the reaction Fe^(2+)+Zn rarr Zn^(2+)+Fe is -

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Under what condition will the terminal potential difference be more than the emf of a cell?