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Nitrobenzene does not undergo Friedel-Cr...

Nitrobenzene does not undergo Friedel-Crafts alkylation. Give reasons.

Text Solution

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Due to powerful electron withdrawing effect of the `-NO_(2)` group, the benzene ring in `C_(6)H_(5)NO_(2)` is deactivated towards Friedel Craft’s alkylation and hence it is used as a solvent in many Fridel-Craft’s reaction.
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Knowledge Check

  • Assertion alkyl benzene is not prepared by Friedel-Crafts alkylation of benzene. Reason Alkyl halides are less reactive than acyl halides in Sn reaction.

    A
    If both Assertion and Reason are true and reason is correct explanation of Assertion
    B
    If both Assertion and Reason are true but reason is not the correct explanation of Assertion
    C
    Assertion is false but reason is true
    D
    If both Assertion and Reason are false
  • Which of the following does not undergo Friedel-Craft's reaction?

    A
    `C_6H_5OH`
    B
    `C_6H_5NO_2`
    C
    `C_6H_5CH_3`
    D
    None of these
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