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What is lanthanoid contraction ?...

What is lanthanoid contraction ?

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Regular decrease in atomic radius with increase in atomic number in f-block elements is called lanthanoid contraction.
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(a) How would you account for the following : (i) Cobalt (II) is stable in aqueous solution but in the presence of strong ligands, it is easily oxidised. (ii) The transition metals form interstitial compounds. (iii) Silver halides find use in photography. (b) What is lanthanoid contraction ? Mention its main consequences.

(a) Why do transition elements show variable oxidation states? (i) Name the element showing maximum number of oxidation states among the first series of transition metals from Sc (Z = 21) to Zn (Z = 30). (ii) Name the element which shows only + 3 oxidation state. (b) What is lanthanoid contraction? Name an important alloy which contains some of the lanthanoid metals.

Knowledge Check

  • Lanthanoid contraction means :

    A
    small atomic sizes of lanthanoid elements
    B
    small ionic size of lanthanoid ions.
    C
    smaller atomic size of lanthanoids as compared to transition element in the same period
    D
    decrease in atomic and ionic radii of the element of lanthanoid series in moving from left to the right.
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