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The outer electronic configurations of t...

The outer electronic configurations of two transition metals are (i) `3d^(5)4s^(2)` and (ii) `3d^(6)4s^(2)` respectively. Based on this information predict the relative stability of +2 and +3 oxidation state of these metals. Which of the two exhibits larger number of oxidation states ?

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Metal with configuration `3d^(5)4s^(2)` will show oxidation state (+2) more readily because of greater stability of half-filled d-orbitals. Metal with configuration `3d^(6)4s^(2)` will be more stable in +3 oxidation state than +2 due because after losing two electrons the configuration of the metal ion will be `3d^(5)`, which is a stable configuration.
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U-LIKE SERIES-THE D-AND F-BLOCK ELEMENTS -SHORT ANSWER QUESTIONS (2 marks each)
  1. When a brown compound of manganese (A) is treated with HCl it gives a ...

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  2. Explain why (i) E^(@) for Mn^(3+)//Mn^(2+) couple is more positive t...

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  3. With the help of ionic equations, describe what happens when (i) pH ...

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  4. Although Zr belongs to 4d and Hf belongs to 5d transition series, but ...

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  5. The outer electronic configurations of two transition metals are (i) 3...

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  6. The second and third rows of transition elements resemble each other m...

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  7. Although Cr^(3+) and Co^(2+) ions have the same number of unpaired ele...

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  8. Although +3 oxidation state is the characteristic oxidation state of l...

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  9. When orange solution containing CrO(7)^(2-) ion is treated with an alk...

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  10. Explain why does the colour of KMnO(4) disappear when oxalic acid is a...

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  11. E^(@) of Cu is + 0.34 V while that of Zn is – 0.76 V. Explain.

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  12. The halides of transition elements become more covalent with increasin...

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  13. Reactivity of transition elements decreases almost regularly from Sc t...

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  14. Explain any one of the following statements : (i) The transition met...

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  15. Answer the following questions : (i) Which element in the first seri...

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  16. How do you account for the following: (i) all scandium salts are whi...

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  17. Why is the +2 oxidation state of manganese quite stable, while the sam...

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  18. While filling up of the electrons in the atomic orbitals, the 4s orbit...

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  19. Write complete equations for (i) Oxidation of Fe^(2+) by Cr(2)O(7)^(...

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  20. Identify the following : (i) Oxoanion of chromium which is stable in...

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