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Account for the following : (i) NH(3) ...

Account for the following :
(i) `NH_(3)` is a stronger base than `PH_(3)`
(ii) Sulphur has a greater tendency for catention than oxygen.
(iii) Bond dissociation energy of `F_(2)` is less than that of `Cl_(2)`.
(OR)
Explain the following situations :
(i) In the structure of `HNO_(3)` moleucle, the `N-O` bond (121 pm) is shorter than the ` N-OH` bond (140 pm).
(ii) `SF_(4)` is easily hydrolysed whereas `SF_(6)` is not easily hydrolysed.
(iii) `XeF_(2)` has a straight linear structure and not a bent angular structure.

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Account for the following : (i) NH_(3) is a stronger base than PH_(3) (ii) Sulphur has a greater tendency for catenation than oxygen. (iii) Bond dissociation energy of F_(2) is less than that of Cl_(2) .

Explain the following situations : (i) In the structure of HNO_(3) molecule , the N-O bond (121 pm) is shorter than N-OH bond (140pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

Explain the following situations : (i) In the structure of HNO_(3) molecule , the N-O bond (121 pm) is shorter than N-OH bond (140pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

Bond dissociation energy of F_2 is less than Cl_2 .

Explain the following situations: in the structure of HNO_3 molecule, the N-O bond (121 pm) is shorter than N-OH bond (140 pm).

Account for the following : NH_3 is a stronger base than PH_3 .

Explain why Bond dissociation energy of F_2 is less than that of Cl_2 ?