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The degree of dissociation of PC1(5) (al...

The degree of dissociation of `PC1_(5)` `(alpha)` obeying the equilibrium, `PC1_(5)hArrPC1_(3) + C1_(2)`, is approximately related to the pressure at equilibrium by (given `alpha ltlt 1`) :

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If dissociation for reaction, PC1_(5)hArrPC1_(3) + C1_(2) is 20% at 1 atm pressure. Calculate K_(c) .

Assertion: Association of an inert gas at constant pressure to dissociation equilibrium of PC1_(5) hArr PC1_(3) + C1_(2) favours forward reaction. Reason: K_(c) =(alpha^(2))/(V(1 - alpha)) for the dissociation equilibrium of PC1_(5) where alpha is degree of dissociation of PC1_(5) .