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Consider an ionic solid that dissolves i...

Consider an ionic solid that dissolves in water according to the equation:
`M_(n)X_(m(s)) nM_(aq)^(m+)n + mX_(aq)^(n-)` . The equilibrium constant for this reaction, `K _(sp)=[M^(m+)]^(n) [X^(n-)]^(m) ` is known as the solubility product of `M_(n), X_(m)`. The form of this euquilibrium is important in understanding effects such as the influence of pH, complex fomation and common ion cffect. Equilibrium constant in solution should be written correctly using activities and not concentrations. The difference between thesc quantities is large in concentrated ionic solutions and `K_(sp)` is quantitatively reliable as a guide of solubilities only for very dilute solutions, If solubility product of AB type salt is `4xx 10^(-10)` at `18^(@)`C, and M.W of AB is 143.5 g/mol.
If ppt. of AB is washed with 5 lit water, loss in wt. of ppt. of AB is

A

`10^(-4)` mol/lit

B

`10^(-4)` gm

C

`10^(-4)` mol

D

`10^(-4)` mg

Text Solution

Verified by Experts

The correct Answer is:
C
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Consider an ionic solid that dissolves in water according to the equation: M_(n)X_(m(s)) nM_(aq)^(m+)n + mX_(aq)^(n-) . The equilibrium constant for this reaction, K _(sp)=[M^(m+)]^(n) [X^(n-)]^(m) is known as the solubility product of M_(n), X_(m) . The form of this euquilibrium is important in understanding effects such as the influence of pH, complex fomation and common ion cffect. Equilibrium constant in solution should be written correctly using activities and not concentrations. The difference between thesc quantities is large in concentrated ionic solutions and K_(sp) is quantitatively reliable as a guide of solubilities only for very dilute solutions, If solubility product of AB type salt is 4xx 10^(-10) at 18^(@) C, and M.W of AB is 143.5 g/mol. The solubility in g/lit of AB is

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AAKASH SERIES-IONIC EQUILLIBRIUM-LECTURE SHEET (EXERCISE-IV) ( Straight Objective Type Questions )
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  2. Let the solubility of an aqueous solution of Mg(OH)(2), be "X^(@) then...

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  3. The correct representation for solubility product of SnS(2) , is

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  4. Which of the following has the lowest value of K at 25^(@) C?

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  5. Which of the following is most soluble ?

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  6. pH of saturated Mg(OH)(2), solution is 12, then

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  7. Which of the following is/are true for an acid- base titration?

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  8. Let the colour of the indicator (Hin colourles) will be visible only w...

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  9. The dissociation constant of an indicator 'InH' is 10^(5. Then

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  10. A solution which remains in equilibrium with undissolved solute is sai...

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  11. A solution which remains in equilibrium with undissolved solute is sai...

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  12. A solution which remains in equilibrium with undissolved solute is sai...

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  13. Consider an ionic solid that dissolves in water according to the equat...

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  14. Consider an ionic solid that dissolves in water according to the equat...

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  15. The solubility product of SrF(2) in water is 8xx10^(-10) Calculate it...

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  16. Solubility products of ACO(3), BSO(4), and ASO(4), are 4 xx 10^(-10), ...

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  17. The K, of an indicator HIn is 9 x 10^(4), The percentage of the basic ...

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  18. Calculate the pH at which an acid indicator with K(a), = 1.0 xx 10^(-5...

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  19. K(sp) of M(OH)(x), is 27 xx 10^(-12) and its solubility in water is 10...

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  20. {:("List -I Salt","List -II Kg"),((A) AgCI,P.27S^(4)),((B)PbI(2),Q.108...

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