Home
Class 12
CHEMISTRY
CuSO(4).5H(2)O is blue in colour while C...

`CuSO_(4).5H_(2)O` is blue in colour while `CuSO_(4)` is colourless, why ?

Text Solution

Verified by Experts

In `CuSO_(4).5H_(2)O`, water acts as ligand as a result it causes crystal field splitting. Hence d-d transition is possible in `CuSO_(4).5H_(2)O` and shows colour. In the anhydrous `CuSO_(4)` due to the absence of water (ligand), crystal field splitting is not possible and hence no colour.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    U-LIKE SERIES|Exercise LONG ANSWER QUESTIONS-I (3 marks each)|85 Videos
  • COORDINATION COMPOUNDS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST|7 Videos
  • COORDINATION COMPOUNDS

    U-LIKE SERIES|Exercise VERY SHORT ANSWER QUESTIONS (1 mark each)|69 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    U-LIKE SERIES|Exercise LONG ANSWER QUESTIONS - I|21 Videos
  • ELECTROCHEMISTRY

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST (SECTION D)|1 Videos

Similar Questions

Explore conceptually related problems

CuSO_(4).5H_(2)O is blue in colour because

CuSO_(4)*5H_(2)O belongs to

In CuSO_(4).5H_(2)O copper is coordinated to

CuSO_4.5H_2O is represented as

The heat of solution of anhydrous CuSO_(4) is -15.9 kcal and that of CuSO_(4).5H_(2)O is 2.8 kcal. The heat of hydration of CuSO_(4) will be

U-LIKE SERIES-COORDINATION COMPOUNDS-SHORT ANSWER QUESTIONS (2 marks each)
  1. Why do compounds having similar geometry have different magnetic momen...

    Text Solution

    |

  2. The spin only magnetic moment of [MnBr(4)]^(2)- is 5.9 BM. Predict the...

    Text Solution

    |

  3. CuSO(4).5H(2)O is blue in colour while CuSO(4) is colourless, why ?

    Text Solution

    |

  4. Name the type of isomerism when ambidentate ligands are attached to co...

    Text Solution

    |

  5. Write the IUPAC name and draw the structure of coordination entities o...

    Text Solution

    |

  6. Using valence bond theory, predict the shape and magnetism (paramagnet...

    Text Solution

    |

  7. Why are low spin tetrahedral complexes not formed ?

    Text Solution

    |

  8. Using the valence bond approach, deduce the shape and magnetic charact...

    Text Solution

    |

  9. How is the magnitude of Delta(0) affected by (i) nature of ligand and ...

    Text Solution

    |

  10. Using the valence bond approach, deduce the shape and magnetic charact...

    Text Solution

    |

  11. Using valence bond approach, deduce the shape and magnetic behaviour o...

    Text Solution

    |

  12. Using the valence bond approach, predict the shape and magnetic charac...

    Text Solution

    |

  13. Using the valence bond approach, predict the shape and magnetic behavi...

    Text Solution

    |

  14. Using the valence bond approach, deduce the shape and magnetic behavio...

    Text Solution

    |

  15. Deduce the shape and magnetic behaviour of the complex ion [Co(NH(3))(...

    Text Solution

    |

  16. Among [Ag(NH(3))(2)]Cl, [Ni(CN)(4))^(2-) and [CuCl(4)]^(2-) which ha...

    Text Solution

    |

  17. Among [Ag(NH(3))(2)]Cl, [Ni(CN)(4))^(2-) and [CuCl(4)]^(2-) which re...

    Text Solution

    |

  18. Square planar complexes with coordination number 4 exhibit geometrical...

    Text Solution

    |

  19. Using valence bond approach, predict the shape and magnetic character ...

    Text Solution

    |

  20. Explain the following : [Co(NH(3))(6)]^(3+) is diamagnetic, whereas ...

    Text Solution

    |