Home
Class 12
CHEMISTRY
What is meant by crystal field splitting...

What is meant by crystal field splitting energy ? On the basis of crystal field theory, write the electronic configuration of `d^(4)` in terms of `t_(2g)` and `e_(g)` in an octahedral field when
`Delta_(0)gtP`

Text Solution

Verified by Experts

The five d-orbitals in a metal ion are degenerate (of equal energy). But when ligands approach the central metal ion, they experience repulsions. The d-orbitals are split into two groups consisting of three orbitals called `t_(2g)` orbitals and two orbitals called `e_(g)` orbitals. the `e_(g)` orbitals possess greater energy than`t_(2g)` orbitals. Till there are three electrons, they will occupy three `t_(2g)` orbitals singly. If there are 4 electrons in d-orbitals i.e., `d^(4)` configuration, two cases arise.
If `Delta_0 gt P`, then the fourth electron will go to `t_(2g)` orbital, the electronic configuration will be `t_(2g)^(4)e_(g)^(0)` .
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST|7 Videos
  • COORDINATION COMPOUNDS

    U-LIKE SERIES|Exercise SHORT ANSWER QUESTIONS (2 marks each)|54 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    U-LIKE SERIES|Exercise LONG ANSWER QUESTIONS - I|21 Videos
  • ELECTROCHEMISTRY

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST (SECTION D)|1 Videos

Similar Questions

Explore conceptually related problems

What is meant by crystal field splitting energy? On the basis of crystal field theory, write the electronic configuration of d^(4) in terms of t_(2g) and e_(g) in an octahedral field when (i) Delta_(0)gtP (ii) Delta_(0)ltP

On the basis of crystal field theory. Write the electronic confirguration of d^(6) in terms of t_(2g) " and " e_(g) in an octahedral field when D_(0) lt P.

U-LIKE SERIES-COORDINATION COMPOUNDS-LONG ANSWER QUESTIONS-I (3 marks each)
  1. What type of isomerism does it exhibit ?

    Text Solution

    |

  2. Draw the structures of these geometrical isomers.

    Text Solution

    |

  3. What is meant by crystal field splitting energy ? On the basis of crys...

    Text Solution

    |

  4. What is meant by crystal field splitting energy ? On the basis of crys...

    Text Solution

    |

  5. Name the following coordination entities and draw the structures of th...

    Text Solution

    |

  6. Name the following coordination entities and draw the structures of th...

    Text Solution

    |

  7. Name the following coordination entities and draw the structures of th...

    Text Solution

    |

  8. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Oxidati...

    Text Solution

    |

  9. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Hybrid ...

    Text Solution

    |

  10. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Magneti...

    Text Solution

    |

  11. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Magneti...

    Text Solution

    |

  12. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Magneti...

    Text Solution

    |

  13. For the complex [Fe(en)(2)Cl(2)]Cl, identify the following : Name of...

    Text Solution

    |

  14. Write the name, stereochemistry and magnetic behaviour of the followin...

    Text Solution

    |

  15. Write the name, stereochemistry and magnetic behaviour of the followin...

    Text Solution

    |

  16. Write the name, stereochemistry and magnetic behaviour of the followin...

    Text Solution

    |

  17. Write the structures and names of all the stereoisomers of the followi...

    Text Solution

    |

  18. Write the structures and names of all the stereoisomers of the followi...

    Text Solution

    |

  19. Write the structures and names of all the stereoisomers of the followi...

    Text Solution

    |

  20. Give the electronic configuration of the d-orbitals of Ti in [Ti(H(2...

    Text Solution

    |