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How would you account for the increasing...

How would you account for the increasing oxidising power in the series `VO_2^(o+)ltCr_2O_7^(2-)< MnO_4^(ɵ)`?

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To account for the increasing oxidizing power in the series \( VO_2^{+} < Cr_2O_7^{2-} < MnO_4^{-} \), we can analyze the oxidation states of the central metal ions, their electronic configurations, and the stability of their reduced forms. ### Step-by-Step Solution: 1. **Identify the Oxidation States:** - For \( VO_2^{+} \): - Let the oxidation state of vanadium (V) be \( x \). - The equation is: \( x + 2(-2) = +1 \). ...
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How would you account for the following? The oxidising power of the following three oxo ions in the series follows the order : VO_(2)^(+)ltCr_(2)O_(7)^(2-)ltMnO_(4)^(-)

(a) Complete the following chemical equations: (i) Cr_(2) O_(7)^(2-) (aq) + H_(2) S(g) + H^(+) (aq) to (ii) Cu^(2+)(aq) + I^(-) (aq) to (b) How would you account for the following : (i) The oxidising power of oxoanions are in the order VO_(2)^(+) lt Cr_(2)O_(7)^(2-) lt Mn O_(4)^(-) (ii) The third ionization enthalpy of manganess (Z = 25) is exceptionally high. (iii) Cr^(2+) is a stronger reducing agent than Fe^(2+) .

How would you expect the bond strength to change in the series C_(2) to C_(2)^(-) to C_(2)^(2-) ?

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Following order is observed in oxidising power of certain ions : VO_2^(+) lt Cr_2O_7^(2-) lt MnO_4^(-) The reason for this increasing order of oxidising power is

(a) What happens when (i) Manganate ions (MnO_(4)^(2-)) undergoes disproportionation reaction in acidic medium ? (ii) Lanthanum is heated with Sulphur? (b) Explain the following trends in the properties of the members of the First series of transition elements: (i) E^(@) (M^(2+)//M) value for copper is positive (+ 0.34 V) in contrast to the other members of the series. (ii) Cr^(2+) is reducing while Mn^(3+) is oxidising, though both have d^(4) configuration. (iii) The oxidising power in the series increases in the order VO_(2)^(+) lt Cr_(2)O_(7)^(2-) lt MnO_94)^(-) .

Arrange the following : Increasing oxidising power F_(2),Cl_(2),Br_(2),I_(2)

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How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements ?

Which of the following increasing order of oxidising power is correct for the following species? VO_(2)^(+),MnO_(4)^(-),Cr_(2)O_(7)^(2-)

NCERT ENGLISH-THE D AND F BLOCK ELEMENTS-Exercise
  1. How would you account for the increasing oxidising power in the series...

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  2. Write down the electronic configuration of: (i). Cr^(3+) (ii). Prn...

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  3. Why are Mn^(2+) compounds more stable than Fe^(2+) toward oxidation to...

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  4. Explain briefly how +2 state become more and stable in the first half ...

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  5. To what extent do the electronic configurations, decide the stability ...

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  6. What may be the stable oxidation state of the transition element with ...

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  7. Name the oxometal anions of the first series of the transition metals ...

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  8. What is lanthanoid contraction? What are the consequences of lanthanol...

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  9. What are the characteristics of th transition elements and why are the...

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  10. In What way is the electronic configuration of the transition elements...

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  11. What are the different oxidation states exhibited by the lanthanoids?

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  12. Explain gives reason. (a) Transition metal and many of their compoun...

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  13. What are interstitial compounds? Why are such compounds well known for...

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  14. How is the variability in oxidation states of transition metals differ...

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  15. Describe the preparation of potassium dichromate from iron chromite or...

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  16. Describe the oxidising action of potassium dichromate and write the io...

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  17. Describe the preparation of potassium permanganate. How does the acidi...

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  18. For (M^(2+))/(M) and (M^(3+))/(M^(2+)) systems the E^(ɵ) values for so...

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  19. Predict which of the followingwill be coloured in aqueous solution? T...

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  20. Compare the stability of +2 oxidation state for the elements of the fi...

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  21. Compare the chemistry of actinoids with that of the lanthanoids with s...

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