Home
Class 12
CHEMISTRY
In the series Sc(Z=21) to Zn(Z=30) the e...

In the series `Sc(Z=21)` to `Zn(Z=30)` the enthalpy of atomisation of zinc is the lowest, i.e., 126 kJ `mol^(-1)`. Why?

Text Solution

AI Generated Solution

To understand why the enthalpy of atomization of zinc (Zn) is the lowest among the series from scandium (Sc, Z=21) to zinc (Zn, Z=30), we can break down the explanation into several key steps: ### Step 1: Understanding Enthalpy of Atomization The enthalpy of atomization is the energy required to convert one mole of a solid element into its gaseous atoms. It is a measure of the strength of the bonds holding the atoms together in the solid state. **Hint:** Think of enthalpy of atomization as a measure of how tightly atoms are held together in a solid. ### Step 2: Metallic Bonding and its Relation to Atomization ...
Promotional Banner

Topper's Solved these Questions

  • THE D AND F BLOCK ELEMENTS

    NCERT ENGLISH|Exercise Exercise|38 Videos
  • SURFACE CHEMISTRY

    NCERT ENGLISH|Exercise Exercise|35 Videos
  • THE P-BLOCK ELEMENTS

    NCERT ENGLISH|Exercise EXERCISE|74 Videos

Similar Questions

Explore conceptually related problems

Assertion : In the series Sc to Zn, the enthalpy of atomisation of zinc is the lowest. Reason : Zinc has greater number of unpaired electrons.

Why is enthalpy of atomisation is the lowest for Zn in 3d series of transition elements ?

Bond dissociation enthalpies of H_(2(g)) and N_(2(g)) are "426.0 kJ mol"^(-1) and "941.8 kJ mol"^(-1) , respectively, and enthalpy of formation of NH_(3(g))" is "-"46 kJ mol"^(-1) . What are the enthalpy of atomisation of NH_(3(g)) and the average bond enthalpy of N-H bond respectively ( in kJ "mol"^(-1) )?

The DeltaH_(f)^(0)(KF,s) is -563 kJ mol^(-1) . The ionization enthalpy of K(g) is 419 kJ mol^(-1) . and the enthalpy of sublimation of potassium is 88 kJ mol^(-1) . The electron affinity of F(g) is 322 kJ mol^(-1) and F-F bond enthalpy is 158 kJ mol^(_1) . Calculate the lattice enthalpy of KF(s) . The given data are as follows: (i) K(s)+1//2F_(2)(g)rarrKF(s)" "DeltaH_(f)^(0)= -563 kJ mol^(-1) (ii) K(g)rarrK^(+)(g)+e^(-)" "Delta_("Ioniz")^(0)=419 kJ mol^(-1) (iii) K(s)rarrK(g)" "DeltaH_("sub")^(0)=88kJ mol^(-1) (iv) F(g)+e^(-)rarrF^(-)(g)" "DeltaH_(eg)^(0)= -322 kJ mol^(-1) (v) F_(2)(g)rarr2F(s)" "DeltaH_("diss")^(0)= 158 kJ mol^(-1) (vi) K^(+)(g)+F^(-)(g)rarrKF(s)" " DeltaH_(L)^(0)=?

In the 3d series (Sc = 21 to Zn = 30) : (i) Which elements shows maximum number of oxidation states ? (ii) Which elements shows only +3 oxidation state ? (iii) Which elements has the lowest enthalpy of atomization?

(a) Why do transition elements show variable oxidation states? (i) Name the element showing maximum number of oxidation states among the first series of transition metals from Sc (Z = 21) to Zn (Z = 30). (ii) Name the element which shows only + 3 oxidation state. (b) What is lanthanoid contraction? Name an important alloy which contains some of the lanthanoid metals.

From the following data, calculate the enthalpy change for the combustion of cyclopropane at 298K . The enthalpy of formation of CO_(2(g)),H_(2)O_((l)) and Propen e_((g)) are -393,-285.8 and 20.42 kJ mol^(-1) respectively. The enthalpy of isomerisation of cyclopropane to propene is -33.0kJ mol^(-1)

Bond dissociation enthalpies of H_(2)(g) and N_(2)(g) are 436.0 kJ mol^(-1) and 941.8 kJ mol^(-1) , respectively, and ethalpy of formation of NH_(3)(g) is -46kJ mol^(-1) . What is the enthalpy fi atomisation of NH_(3)(g) ?. What is the avergae bond ethalpy of N-H bond?

Answer the following questions (i) Which element of the first transition series has highest second ionisation enthalpy? (ii) Which element of the first transition series has highest third ionisation enthalpy? (iii) Which element of the first transition series has lowest enthalpy of atomisation? (b) Identify the metal and justify your answer. (i) Carbonyl M(CO)_(5) (ii) MO_(3)F

Zinc reacts with dilute hydrochloric acid to give hydrogen at 17^(@)C . The enthalpy of the reaction is -12.00 kJ mol^(-1) of zinc and entropy change equals 50 J K^(-1) mol^(-1) for the reaction. Calculate the free enegry change and predict whether the reaction is spontaneous or not.

NCERT ENGLISH-THE D AND F BLOCK ELEMENTS-Exercise
  1. In the series Sc(Z=21) to Zn(Z=30) the enthalpy of atomisation of zinc...

    Text Solution

    |

  2. Write down the electronic configuration of: (i). Cr^(3+) (ii). Prn...

    Text Solution

    |

  3. Why are Mn^(2+) compounds more stable than Fe^(2+) toward oxidation to...

    Text Solution

    |

  4. Explain briefly how +2 state become more and stable in the first half ...

    Text Solution

    |

  5. To what extent do the electronic configurations, decide the stability ...

    Text Solution

    |

  6. What may be the stable oxidation state of the transition element with ...

    Text Solution

    |

  7. Name the oxometal anions of the first series of the transition metals ...

    Text Solution

    |

  8. What is lanthanoid contraction? What are the consequences of lanthanol...

    Text Solution

    |

  9. What are the characteristics of th transition elements and why are the...

    Text Solution

    |

  10. In What way is the electronic configuration of the transition elements...

    Text Solution

    |

  11. What are the different oxidation states exhibited by the lanthanoids?

    Text Solution

    |

  12. Explain gives reason. (a) Transition metal and many of their compoun...

    Text Solution

    |

  13. What are interstitial compounds? Why are such compounds well known for...

    Text Solution

    |

  14. How is the variability in oxidation states of transition metals differ...

    Text Solution

    |

  15. Describe the preparation of potassium dichromate from iron chromite or...

    Text Solution

    |

  16. Describe the oxidising action of potassium dichromate and write the io...

    Text Solution

    |

  17. Describe the preparation of potassium permanganate. How does the acidi...

    Text Solution

    |

  18. For (M^(2+))/(M) and (M^(3+))/(M^(2+)) systems the E^(ɵ) values for so...

    Text Solution

    |

  19. Predict which of the followingwill be coloured in aqueous solution? T...

    Text Solution

    |

  20. Compare the stability of +2 oxidation state for the elements of the fi...

    Text Solution

    |

  21. Compare the chemistry of actinoids with that of the lanthanoids with s...

    Text Solution

    |