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What are the necessary conditions for any system to be aromatic?

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To determine whether a system is aromatic, it must satisfy the following three necessary conditions: 1. **Planarity**: The molecule must be planar, meaning all the atoms in the ring must lie in the same plane. This allows for effective overlap of p-orbitals, which is essential for delocalization of electrons. 2. **Complete Delocalization**: The molecule should have a completely delocalized ring of π electrons. This means that the electrons are not localized between two atoms but are spread out over the entire ring structure, allowing for resonance. 3. **Hückel's Rule**: The system must adhere to Hückel's rule, which states that the molecule should have a specific number of π electrons, given by the formula \(4n + 2\), where \(n\) is a non-negative integer (0, 1, 2, ...). This rule helps to determine the stability and aromatic character of the compound. Thus, for a compound to be classified as aromatic, it must be planar, have a completely delocalized ring, and satisfy Hückel's rule by having \(4n + 2\) π electrons. ---

To determine whether a system is aromatic, it must satisfy the following three necessary conditions: 1. **Planarity**: The molecule must be planar, meaning all the atoms in the ring must lie in the same plane. This allows for effective overlap of p-orbitals, which is essential for delocalization of electrons. 2. **Complete Delocalization**: The molecule should have a completely delocalized ring of π electrons. This means that the electrons are not localized between two atoms but are spread out over the entire ring structure, allowing for resonance. 3. **Hückel's Rule**: The system must adhere to Hückel's rule, which states that the molecule should have a specific number of π electrons, given by the formula \(4n + 2\), where \(n\) is a non-negative integer (0, 1, 2, ...). This rule helps to determine the stability and aromatic character of the compound. ...
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NCERT ENGLISH-HYDROCARBONS-EXERCISE
  1. An alkene ‘A’ contains three C – C, eight C – H (sigma) bonds and one...

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  2. Propanal and pentan-3-one are the ozonolysis products of an alkene? Wh...

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  3. Write chemical equations for combustion reaction of the following hydr...

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  4. Draw the cis and trans structures of hex-2-ene. Which isomer will have...

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  5. Why is benzene extra ordinarily stable though it contains three double...

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  6. What are the necessary conditions for any system to be aromatic?

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  7. Explain why the following systems are not aromatic?

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  8. How will you convert benzene into (i) p-nitrobromobenzene (ii) m-...

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  9. In the alkane H3C-CH(2)-C(CH(3))2-CH(2)-CH(CH(3))2, identify 1^(@),2^(...

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  10. What effect does branching of an alkane chain has on its boiling point...

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  11. Addition of HBr to propene yields 2-bromopropane, while in the presenc...

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  12. Write down the products of ozonolysis of 1, 2-dimethylbenzene (o-xylen...

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  13. Arrange benzene, n-hexane and ethyne in decreasing order of acidic beh...

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  14. Why does benzene undergo electrophilic substitution reactions easily a...

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  15. How would you convert the following compounds into benzene? (i) Ethy...

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  16. Write structures of all the alkenes which on hydrogenation give 2-meth...

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  17. Arrange the following set of compounds in order of their decreasing re...

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  18. Out of benzene, m–dinitrobenzene and toluene which will undergo nitrat...

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  19. Suggest the name of a Lewis acid other than anhydrous aluminium chlori...

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  20. Why is Wurtz reaction not preferred for the preparation of alkanes con...

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