Home
Class 12
CHEMISTRY
Nitrogen exists as diatomic molecule and...

Nitrogen exists as diatomic molecule and phosphorus as `P_(4)`. Why ?

Text Solution

Verified by Experts

Nitrogen owing to its small size has a tendency to form `ppi−ppi` multiple bonds with itself. Nitrogen thus forms a very stable diatomic molecule, `N_(2)`. On moving down a group, the tendency to form `ppi−ppi` bonds decreases (because of the large size of heavier elements). Therefore, phosphorus (like other heavier metals) exists in the `P_(4)`state.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    NCERT ENGLISH|Exercise EXERCISE|74 Videos
  • THE D AND F BLOCK ELEMENTS

    NCERT ENGLISH|Exercise Exercise|38 Videos
  • THE SOLID STATE

    NCERT ENGLISH|Exercise All Questions|49 Videos

Similar Questions

Explore conceptually related problems

A diatomic molecules has

Why do halogens exist as diatomic molecules ?

Assertion : In atomic form hydrogen consists of one proton and one electron. Reason : In elemental form hydrogen exists as a diatomic molecule and is called dihydrogen.

White phosphorus (P_4) has

Nitrogen and oxygen exist as diatomic but their congeners are P_(4) and S_(8) respectively because :

Why do they exist as monoatoms in molecules?

Which molecule does not exist ?

Which molecule does not exist ?

Nitrogen forms a simple diatomic molecule but other elements of same group do not form. Explain.

Statement-1 : At room temperature oxygen exists as a diatomic gas, where as sulphur exists as solid. Statement-2 : The catenated -O-O-O- chains are less stable as compared to O=O molecule.