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Knowing the electron gain enthalpy value...

Knowing the electron gain enthalpy values for `O rarr O^(Ө)` and `O rarr O^(2-)` as `- 141 kJ mol^-1` and `+ 702 kJ mol^-1` respectively, how can you account for the formation of a large number of oxides having `O^(2-)` species and not `O^(Ө)` ?

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To account for the formation of a large number of oxides containing the `O^(2-)` species instead of `O^(−)`, we can analyze the electron gain enthalpy values and the stability of these species. Here’s a step-by-step breakdown of the reasoning: ### Step 1: Understanding Electron Gain Enthalpy - The electron gain enthalpy for the formation of `O^(−)` from `O` is `-141 kJ mol^-1`. This negative value indicates that the process is exothermic and favorable, meaning that it releases energy when an electron is added to an oxygen atom to form `O^(−)`. - Conversely, the electron gain enthalpy for the formation of `O^(2-)` from `O^(−)` is `+702 kJ mol^-1`. This positive value indicates that the process is endothermic and not favorable, meaning that it requires energy input to add another electron to `O^(−)` to form `O^(2-)`. ### Step 2: Stability of the Species - Despite the unfavorable formation of `O^(2-)`, this ion achieves a noble gas configuration (similar to neon) when it gains two electrons. This configuration is highly stable and energetically favorable in terms of overall stability. ...
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NCERT ENGLISH-THE P-BLOCK ELEMENTS-EXERCISE
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  2. Why is dioxygen a gas but sulphur a solid?

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  3. Knowing the electron gain enthalpy values for O rarr O^(Ө) and O rarr ...

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  4. Which aerosols deplete ozone?

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  5. Describe the manufacture of H(2)SO(4) by contact process?

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  6. How is SO2 an air pollutant?

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  7. Why are halogens strong oxidising agents ?

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  8. Explain why fluorine forms only one oxoacid, HOF.

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  9. Explain why inspite of nearly the same electronegativity, nitrogen for...

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  10. Write two uses of ClO2.

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  11. Why are halogens coloured?

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  12. Write the reactions of F(2) and Cl(2) with water.

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  13. How can you prepare Cl2 from HCl and HCI from Cl2? Write reactions onl...

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  15. What are the oxidation states of phosphorus in the following: (i)H(3...

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  16. Write balanced equation for the following: (i). NaCl is heated with ...

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  17. How are xenon fluorides XeF(2), XeF(4) and XeF(6) obtained?

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  18. With what neutral molecule is ClO^(ɵ) isoelectronic Is that molecule a...

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  19. How are XeO3 and XeOF4 prepared?

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  20. Arrange the following in the order of property indicated for each set:...

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