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Haloalkanes react with KCN to form alkyl...

Haloalkanes react with KCN to form alkyl cyanides as main product while AgCN forms isocyanides as the chief product. Explain.

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To explain why haloalkanes react with KCN to form alkyl cyanides as the main product while AgCN forms isocyanides as the chief product, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Understanding the Reactants**: - Haloalkanes are organic compounds containing a halogen atom (like Cl, Br, or I) attached to an alkane carbon chain. - KCN (potassium cyanide) and AgCN (silver cyanide) are both cyanide sources, but they behave differently in reactions due to their structural characteristics. ...
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NCERT ENGLISH-HALOALKANES AND HALOARENES-Exercise
  1. Haloalkanes react with KCN to form alkyl cyanides as main product whil...

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  2. Write structures of the following compounds: (i) 2-Chloro-3-methylpe...

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  3. Why is sulphuric acid not used during the reaction of alcohols with KI...

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  4. Write structures of different dihalogen derivatives of propane.

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  5. Among the isomeric alkanes of molecular formula C(5)H(12), identify th...

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  6. Draw the structures of major monohalo products in each of the followin...

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  7. Arrange each set of compounds in order of increasing boiling points. ...

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  8. Which alkyl halide from the following pairs would you expect to react ...

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  9. In the following pairs of halogen compounds, which compound undergoes ...

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  10. Identify A, B, C, D, E, R and R^(1) in the following:

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  11. Name the following halides according to IUPAC system and classify them...

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  12. Give the IUPAC names of the following compounds: (i) CH(3)CH(Cl)CH(B...

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  13. Write the structures of the following organic halogen compounds. (i)...

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  14. Which one of the following has the highest dipole moment? (i) CH(2)C...

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  15. A hydrocarbon C(5)H(10) does not react with chlorine in dark but gives...

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  16. Write the isomers of the compound having formula C(4)H(9)Br.

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  17. Write the equations for the preparation of 1-iodobutane from (i) 1-b...

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  18. What are ambident nucleophiles? Explain with an example.

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  19. Which compound in each of the following pairs will react faster in S(N...

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  20. Predict all the alkenes that would be formed by dehydrohalogenation of...

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  21. How will you bring about the following conversions? (i) Ethanol to ...

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