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What are ambident nucleophiles? Explain ...

What are ambident nucleophiles? Explain with an example.

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Nucleophiles which can attack through two different sites are called ambident nucleophiles. For example, cyanide ion is a resonance hybrid of the following two structures :
`overset(-):C-=N:harr:C=overset(..)Noverset(-):`
It can attack through carbon to from cyanide and through N to form is ) cyanide.
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NCERT ENGLISH-HALOALKANES AND HALOARENES-Exercise
  1. Write the structures of the following organic halogen compounds. (i)...

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  2. Which one of the following has the highest dipole moment? (i) CH(2)C...

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  3. A hydrocarbon C(5)H(10) does not react with chlorine in dark but gives...

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  4. Write the isomers of the compound having formula C(4)H(9)Br.

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  5. Write the equations for the preparation of 1-iodobutane from (i) 1-b...

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  6. What are ambident nucleophiles? Explain with an example.

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  7. Which compound in each of the following pairs will react faster in S(N...

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  8. Predict all the alkenes that would be formed by dehydrohalogenation of...

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  9. How will you bring about the following conversions? (i) Ethanol to ...

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  10. Explain why (i) the dipole moment of chlorobenzene is lower than tha...

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  11. Give the uses of freon 12, DDT, carbon tetrachloride and iodoform.

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  12. Write the main product (s) in each of the following reaction : (i) ...

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  13. Write the mechanism of the following reaction: nBuBr + KCN overset(E...

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  14. Rearrange the compounds of each of the following sets in order of reac...

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  15. Out of C(6)H(5)CH(2)Cl and C(6)H(5)CHClC(6)H(5), which is more easily ...

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  16. p-Dichlorobenzene has higher m.p. than those of o- and m-isomers. Disc...

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  17. How the following conversions can be carried out? (i) Propene to pro...

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  18. The treatment of alkyl chlorides with aqueous KOH leads to the formati...

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  19. Primary alkyl halide C4 H9Br : (a) reacted with alcoholic KOH to gi...

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  20. What happens when (i) n-butyl chloride is treated with alcoholic KOH...

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