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Give two reactions that show the acidic ...

Give two reactions that show the acidic nature of phenol. Compare the acidity of phenol with that of ethanol.

Text Solution

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The reactions showing acidic nature of phenol are :
(a) Reaction with sodium : Phenol reacts with active metals like sodium to liberate H, gas.

(b) Reaction with NaOH : Phenol dissolves in NaOH to form sodium phenoxide and water.

Phenol is more acidic than ethanol. This is due to the reason that phenoxide ion after the loss of a proton from phenol is stabilized reasonance, while ethoxide ion left after less of a proton from ethanol, is not.
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Knowledge Check

  • Which of the following substance will increase the acidity of phenol ?

    A
    Dil. `H_2SO_4`
    B
    Dil. HCl
    C
    conc. `H_2SO_4`
    D
    conc. `CH_3COOH`
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