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Out of the following two coordination en...

Out of the following two coordination entities Which is chiral (optically active)
(a) `cis-[CrCI_(2)(OX)_(2)]^(3-)`
(b) `trans -[CrCI_(2)(OX)_(2))]^(3-)` .

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AI Generated Solution

To determine which of the two coordination entities is chiral (optically active), we need to analyze their structures. The two entities given are: (a) `cis-[CrCl₂(ox)₂]^(3-)` (b) `trans-[CrCl₂(ox)₂]^(3-)` ### Step-by-Step Solution: **Step 1: Understand the Coordination Geometry** ...
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IUPAC name of complex ion [CrCl_(2)(Ox)_(2)]^(3-) is

Total acyclic optically active isomers of C_(3)H_(2)D_(2) are :

Name the following coordination entities and draw the structures of their stereoisomers : (i) [Co(en)_(2)Cl_(2)]^(+) (en = ethane-1,2-diamine (ii) [Cr(C_(2)O_(4))_(3)]^(3-) (iii) [ Co(NH_(3))_(3)Cl_(3)] (Atomic number Cr = 24 , Co = 27)

Total number of complexes among the following which are opticaly active? (i) [Cr(O x)_(3)]^(3-) (ii) cis- [Pt(Cl_(2))(en)] (iii) cis [Rh(Cl_(2))(NH_(3))_(4)]^(+) (iv) Ru(dipy)_(3)]^(3+) (v) cis [Co(NO_(2))_(3)(dien)] (vi) Trans- [Co(NO_(2))_(3)(dien)] (vii) cis [Co(NO_(2))_(3)(NH_(3))_(3)]

Which of the following can exhibit optical isomerism: (i) [Cr(gly)_3]^0 (ii) [CoBr_(2)CI_(2)(SCN)_(2)]^(3-) (iii) [Co(en)_(3)]^(3+) (iv) Na[PtBrCI(NO_(2))(NH_(3))]

Which of the following complex compounds exhibits cis-trans isomerism (a) [PtCI_(2)(NH_(3))_(2)] (b) [PdCI_(2)BrI] (c ) [Pt(NH_(3))(py)(CI)(Br)] All ofh these .

Specify the oxidation numbers of the metals in the following coordination entities: (i). [Co(H_2O)(CN)(en)_2]^(2+) (ii). [CoBr_2(en)_2]^(o+) (iii). [PtCl_4]^(2-) (iv). K_3[Fe(CN)_6] (v). [Cr(NH_3)_3Cl_3]

NCERT ENGLISH-COORDINATION COMPOUNDS-Exercise
  1. Out of the following two coordination entities Which is chiral (optica...

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  2. Wrtie the formulas for the following coordination compounds: (i). Te...

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  3. Write the IUPAC names of the following coordiantion compounds: (i) [...

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  4. Indicate the type of isomerism exhibited by the following complexes an...

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  5. Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation ...

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  6. Deduce the structures of [NiCl(4)]^(2-) and [Ni (CN)(4)]^(2-) consider...

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  7. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamagnetic though...

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  8. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  9. Explain [Co(NH3)6]^(3+) is an inner orbital complex whereas [Ni(NH3)6]...

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  10. Predict the number of unpaired electrons in the square planar [Pt(CN)4...

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  11. The hexaquo manganese(II) ion contains five unpaired electrons, while ...

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  12. WERNER’S THEORY OF COORDINATION COMPOUNDS

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  13. FeSO4 solution mixed with (NH4)2SO4 solution is 1:1 molar ratio gives ...

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  14. Explain with two examples each of the following: coordination entity, ...

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  15. What is meant by unidentate and ambidentate ligands? Give two examples...

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  16. Specify the oxidation numbers of the metals in the following coordinat...

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  17. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  18. Using IUPAC norms write the systematic names of the following: (i). ...

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  19. List various types of isomerism possible for coordination compounds, g...

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  20. How many geometrical isomers are possible in the following corrdinatio...

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  21. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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