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The hexaquo manganese(II) ion contains f...

The hexaquo manganese(II) ion contains five unpaired electrons, while the hexacyanoion contains only one unpaired electron. Explain using the crystal field theory.

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To explain why the hexaquo manganese(II) ion contains five unpaired electrons while the hexacyano manganese(II) ion contains only one unpaired electron using crystal field theory, we can follow these steps: ### Step 1: Determine the Electron Configuration of Manganese - The atomic number of manganese (Mn) is 25. In its neutral state, the electron configuration is: \[ \text{Mn: } [\text{Ar}] 3d^5 4s^2 \] - In the +2 oxidation state (as in both complexes), manganese loses two electrons, typically from the 4s orbital first, resulting in: ...
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NCERT ENGLISH-COORDINATION COMPOUNDS-Exercise
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  2. Predict the number of unpaired electrons in the square planar [Pt(CN)4...

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  3. The hexaquo manganese(II) ion contains five unpaired electrons, while ...

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  4. WERNER’S THEORY OF COORDINATION COMPOUNDS

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  5. FeSO4 solution mixed with (NH4)2SO4 solution is 1:1 molar ratio gives ...

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  6. Explain with two examples each of the following: coordination entity, ...

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  7. What is meant by unidentate and ambidentate ligands? Give two examples...

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  8. Specify the oxidation numbers of the metals in the following coordinat...

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  9. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  10. Using IUPAC norms write the systematic names of the following: (i). ...

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  11. List various types of isomerism possible for coordination compounds, g...

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  12. How many geometrical isomers are possible in the following corrdinatio...

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  13. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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  14. Draw all the isomers (geometrical and optical) of: (i) [CoCl(2)(en)(...

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  15. Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how man...

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  16. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  17. What is the coordination entity formed when excess of aqueous KCN is a...

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  18. Discuss the nature of bonding in the following coordination entities o...

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  19. Draw figure to show the splitting of d orbitals in an octahedral cryst...

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