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Draw the structures of optical isomers o...

Draw the structures of optical isomers of:
(i). `[Cr(C_2O_4)_3]^(3-)`
(ii). `[PtCl_2(en)_2]^(2+)`
(iii). `[Cr(NH_3)_2Cl_2(en)]^(o+)`

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To solve the problem of drawing the structures of optical isomers for the given coordination compounds, we will follow a systematic approach for each compound. ### (i) Structure of `[Cr(C_2O_4)_3]^(3-)` **Step 1:** Identify the coordination number and geometry. - Chromium (Cr) in this complex is surrounded by three bidentate oxalate ligands (C2O4), leading to a coordination number of 6. The geometry is octahedral. **Step 2:** Draw the basic structure. ...
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Draw the structure of optical isomers of (i) [PtCl_(2)(en)_(2)]^(2+) (ii). [Cr(NH_(3))_2 Cl_(2)(en)]^(+)

Draw the structure of optical isomers of each of the following complex ion: [Cr(C_2O_4)_3]^(3-)

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Indicate the type of isomerism exhibited by the following complexes and draw the structures for these isomers: (i) K[Cr(H_(2)O)_(2)(C_(2)O_(4))_(2) (ii) [Co(en)_(3)]Cl_(3) (iii) [Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2) (iv) [Pt(NH_(3))(H_(2)O)Cl_(2)]

Draw all the isomers (geometrical and optical) of: (i) [CoCl_(2)(en)_(2)]^(+) (ii) [Co(NH_(3))Cl(en)_(2)]^(2+) (iii) [Co(NH_(3))_(2)Cl_(2)(en)]^(+)

Total number of complexes among the following which are opticaly active? (i) [Cr(O x)_(3)]^(3-) (ii) cis- [Pt(Cl_(2))(en)] (iii) cis [Rh(Cl_(2))(NH_(3))_(4)]^(+) (iv) Ru(dipy)_(3)]^(3+) (v) cis [Co(NO_(2))_(3)(dien)] (vi) Trans- [Co(NO_(2))_(3)(dien)] (vii) cis [Co(NO_(2))_(3)(NH_(3))_(3)]

The possible number of the optical isomers in [Cr(en)_(2)CI_(2)]^(o+) is .

Name the following coordination entities and draw the structures of their stereoisomers : (i) [Co(en)_(2)Cl_(2)]^(+) (en = ethane-1,2-diamine (ii) [Cr(C_(2)O_(4))_(3)]^(3-) (iii) [ Co(NH_(3))_(3)Cl_(3)] (Atomic number Cr = 24 , Co = 27)

Specify the oxidation numbers of the metals in the following coordination entities: (i). [Co(H_2O)(CN)(en)_2]^(2+) (ii). [CoBr_2(en)_2]^(o+) (iii). [PtCl_4]^(2-) (iv). K_3[Fe(CN)_6] (v). [Cr(NH_3)_3Cl_3]

State the kind of isomerism possible for the following [Cr(en)_(3)]^(3+) (ii) [Cr(NH_(3))_(4)CI(Br)]^(+) (iii) [Cr(NH_(3))_(4)Br_(2)]_(2)SO_(4)

NCERT ENGLISH-COORDINATION COMPOUNDS-Exercise
  1. List various types of isomerism possible for coordination compounds, g...

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  2. How many geometrical isomers are possible in the following corrdinatio...

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  3. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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  4. Draw all the isomers (geometrical and optical) of: (i) [CoCl(2)(en)(...

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  5. Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how man...

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  6. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  7. What is the coordination entity formed when excess of aqueous KCN is a...

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  8. Discuss the nature of bonding in the following coordination entities o...

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  9. Draw figure to show the splitting of d orbitals in an octahedral cryst...

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  10. What is spectrochemical series? Explain the difference between a weak ...

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  11. The magnitude of CFSE (Crystal Field Splitting Energy , Delta(0)) can ...

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  12. [Cr(NH3)6]^(3+) is paramagnetic while [Ni(CN)4]^(2-) is diamagnetic. E...

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  13. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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  14. [Fe(CN)(6)]^(4-) and [Fe(H(2)O)(6)]^(2+) are of different colours in d...

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  15. BONDING IN METAL CARBONYLS

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  16. Give the oxidation state, d-orbitals occupation and coordination numbe...

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  17. Wrtie down the IUPAC name for each of the following complexes and indi...

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  18. Explain the violet colour of the complex [Ti(H(2)O)(6)]^(3+) on the ba...

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  19. What is meant by the chelate effect? Give and example.

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  20. Discuss briefly giving an example in each case the role of coordinatio...

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