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[Cr(NH3)6]^(3+) is paramagnetic while [N...

`[Cr(NH_3)_6]^(3+)` is paramagnetic while `[Ni(CN)_4]^(2-)` is diamagnetic. Explain why?

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To explain why `[Cr(NH_3)_6]^(3+)` is paramagnetic while `[Ni(CN)_4]^(2-)` is diamagnetic, we can follow these steps: ### Step 1: Determine the electronic configuration of Chromium in `[Cr(NH_3)_6]^(3+)` - Chromium (Cr) has an atomic number of 24. Its ground state electronic configuration is: \[ \text{Cr: } [Ar] 4s^1 3d^5 \] - In the complex `[Cr(NH_3)_6]^{3+}`, chromium has a +3 oxidation state. This means we need to remove three electrons: ...
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NCERT ENGLISH-COORDINATION COMPOUNDS-Exercise
  1. Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how man...

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  2. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  3. What is the coordination entity formed when excess of aqueous KCN is a...

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  4. Discuss the nature of bonding in the following coordination entities o...

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  5. Draw figure to show the splitting of d orbitals in an octahedral cryst...

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  6. What is spectrochemical series? Explain the difference between a weak ...

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  7. The magnitude of CFSE (Crystal Field Splitting Energy , Delta(0)) can ...

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  8. [Cr(NH3)6]^(3+) is paramagnetic while [Ni(CN)4]^(2-) is diamagnetic. E...

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  9. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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  10. [Fe(CN)(6)]^(4-) and [Fe(H(2)O)(6)]^(2+) are of different colours in d...

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  11. BONDING IN METAL CARBONYLS

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  12. Give the oxidation state, d-orbitals occupation and coordination numbe...

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  13. Wrtie down the IUPAC name for each of the following complexes and indi...

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  14. Explain the violet colour of the complex [Ti(H(2)O)(6)]^(3+) on the ba...

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  15. What is meant by the chelate effect? Give and example.

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  16. Discuss briefly giving an example in each case the role of coordinatio...

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  17. How many ions are produced from the complex Co(NH3)6Cl2 in solution? ...

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  18. Amongst the following ions which one has the highest magnetic moment v...

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  19. Amongst the following, the most stable complex is

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  20. What will be the correct order for the wavelengths of absorption in th...

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