Home
Class 12
CHEMISTRY
On dissolving 2.34g of non-electrolyte s...

On dissolving 2.34g of non-electrolyte solute in 40g of benzene, the boiling point of solution was higher than benzene by 0.81K. Kb value for benzene is 2.53 K `kgmol^(-1)` .Calculate the molar mass of solute. [Molar mass of benzene is 78 `gmol^(-1)`]

Text Solution

Verified by Experts

`M_(2) = (k_(b) xx w_(2) xx 1000)/(Delta T_(b) xx W_(1))`
` = (2.53 xx 2.34 xx 1000)/(0.81 xx 40)`
= `182.72 g " mol"^(-1)`
OR
`Delta T_(b) = K_(b) xx m`
= `K_(b) xx ((w_(2))/(m_(2)))/((w_(1))/(m_(1)))`
`M_(2) = (2.53 xx 2.34 xx 1000)/(0.81 xx 40)`
= 182.7 g `mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • SOLUTIONS

    OSWAAL PUBLICATION|Exercise TOPIC - 3 COLLIGATIVE PROPERTIES , DETERMINATION OF MOLAR MASS, ABNORMAL MOLAR MASS, VAN.T HOFF FACTOR (LONG ANSWER TYPE QUESTIONS - II)|18 Videos
  • SOLUTIONS

    OSWAAL PUBLICATION|Exercise TOPIC - 3 COLLIGATIVE PROPERTIES , DETERMINATION OF MOLAR MASS, ABNORMAL MOLAR MASS, VAN.T HOFF FACTOR (SHORT ANSWER TYPE QUESTIONS)|11 Videos
  • SOLID STATE

    OSWAAL PUBLICATION|Exercise TOPIC -2 (SHORT ANSWER TYPE QUESTIONS)|21 Videos
  • Solved Paper

    OSWAAL PUBLICATION|Exercise Exercise|60 Videos

Similar Questions

Explore conceptually related problems

On dissolving 3.24 g of sulphur in 40 g of benzene,the boiling point of the solution was higher than that of benzene by 0.81K .What is the molecular formula of sulphur? ( K_(b) for benzene = 2.53 K kg mol^(-1) , atomic mass of sulphur = 32 g mol^(-1) ).

Vapour pressure of benzene is 200 mm of Hg. When 2 gram of a non-volatile solute dissolved in 78 gram benzene, benzene has vapour pressure of 195 mm of Hg. Calculate the molar mass of the solute. [Molar mass of benzene is 78 g/ mol^(-1) ]

0.90g of a non-electrolyte was dissolved in 90 g of benzene. This raised the boiling point of benzene by 0.25^(@)C . If the molecular mass of the non-electrolyte is 100.0 g mol^(-1) , calculate the molar elevation constant for benzene.

1.0 g of non - electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.4 K. Find the molar mass of the solute. [Given : Freezing point depression constant of benzene = 5.12 K. kg mol].

The boiling point of benzene is 353.23 K when 1.80 g of a non-volatile, non-ionising solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11 K. Calculate the molar mass of solute. " " [Given K_(b) for benzene = 2.53 K kg mol^(-1) ]

The boiling point of benzene is 353.23 K . When 1.80 g of a non-volatile solute was dissolved in 90 g benzene, the boiling point is raised to 354.11 K . Calculate the molar mass of the solute. ( K_(b) for benzene is 2.53 K kg mol^(-1) )

OSWAAL PUBLICATION-SOLUTIONS-TOPIC - 3 COLLIGATIVE PROPERTIES , DETERMINATION OF MOLAR MASS, ABNORMAL MOLAR MASS, VAN.T HOFF FACTOR (LONG ANSWER TYPE QUESTIONS - I)
  1. The boiling point of benzene is 353.23 K when 1.80 g of a non-volatile...

    Text Solution

    |

  2. Acetone boils at 56.38^(@)C and a solution of 1.41 g of an organic com...

    Text Solution

    |

  3. Calculate the osmotic pressure of 0.05% urea solution in water at 20^(...

    Text Solution

    |

  4. A solution containing 18g of non - volatile non - electrolyte solute i...

    Text Solution

    |

  5. On dissolving 2.34g of non-electrolyte solute in 40g of benzene, the b...

    Text Solution

    |

  6. Determine the osmotic pressure of a solution prepa.red by diHolving 2....

    Text Solution

    |

  7. 1.0 g of non - electrolyte solute dissolved in 50 g of benzene lowered...

    Text Solution

    |

  8. A solution of glycerol (C(3) H(8) O(3)) in water was prepared by disso...

    Text Solution

    |

  9. Calculate the amount of KCl which must be added to 1 kg of water so th...

    Text Solution

    |

  10. At 25^(@)C , the saturated vapour pressure of water is 3.165 k Pa (23....

    Text Solution

    |

  11. Calculate the freezing point of an aqueous solution containing 10.50 g...

    Text Solution

    |

  12. What mass of ethylene glycol (molar mass = 62.0 g mol^(-1) ) must be a...

    Text Solution

    |

  13. 15 g of an unknown molecular substance was dissolved in 450 g of water...

    Text Solution

    |

  14. Vapour pressure of chloroform (CHCl(3)) and dichloromethane (CH(2) Cl(...

    Text Solution

    |

  15. At a given temperature and pressure nitrogen gas is more soluble in wa...

    Text Solution

    |

  16. Match the following if molecular masses of X, Y, Z are same

    Text Solution

    |

  17. At 10^(@) C, the average osmotic pressure of blood is 8.8 atm. Find th...

    Text Solution

    |