ROSENMUND REDUCTION

Reduction OF Organic Compounds : H2/Ni,Pt,Pd,-rosenmund''s reduction,-birch reduction,-Bh3/Thf reduction

Which of the following statement is//are correct. (1) To prepare ethanol, CH_(3)Mgl is treated with the other reagent HCHO. (2) Urotropine is formed by the action of HCHO with NH_(3) (3) The conversion of acid chlorides into aldehydes by reduction is termed Rosenmund's reduction. (4) Aldehyde show reducing properties duet ot their ready conversion into ketons.

Reduction OF Organic Compounds : -1) clemmensen reduction,20 wolf kishner reduction,3)mozingo reduction,4) HI/Redp,5) stephen''''''''s reduction,6)DIBAL-H,7) rosenmund''''''''s reduction,8) reduction OF nitro compounds

What is the function of S or quinoline in inter catalyst Pd-BaSO_4 used in Rosenmund's reduction ?

(a) Why are the boiling points of carboxlic acids higher than those of the corresponding alcohols ? (b ) Define the following terms and write reaction involved in it : ( i) Reimer - Tiemann reaction (ii ) Rosenmund's reduction reaction

(a) Account for the following : (i) Cl-CH_(2)COOH is a stronger acid than CH_(3)COOH (ii) Carboxylic acids do not give reaction of carbonyl group (b) write the chemical equation to illustrate the following name reactions: (i) Rosenmund reduction (ii) Cannizzaro 's reaction (C ) Out of CH_(3)CH_(2)-CO-CH_(2)-CH_(3) and CH_(3)CH_(2)-CH_(2)-CO-CH_(3) which gives iodoform test?

Rosenmund's Reaction