[" 19.For the galvanic cell "],[qquad [" "."Ag|AgCl(s),KCl(0.2M)|KBr(0.001M),AgBr(s)|Ag],[" The anode is "],[[K_(SP)(AgCl)=2.8times10^(-10).K_(SP)(AgBr)=3.3times10^(-13)]],[" (1) "Ag|AgCl," (2) "" Ag "|" AgBr "],[" (3) Cell will not work "]]

For the galvanic cell: Ag(s) | AgBr(aq) | Br^(-)(aq) || Cl^(-)(aq)| AgCl(s)| Ag(s) the value of E_(cell)^(@) at 298 K: [Given : K_(sp) of AgCl =2 xx 10^(-10) . K_(sp) of AgBr = 4 xx 10^(-13) = (2.303R xx 298)/(F) = 0.06 , log 2 = 0.3]

For the galvanic cell : Ag|AgCl(s), KCl (0.2M)||KBr(0.001M), AgBr(s)|Ag, calculate the EMF and assign correct polarity to each electrode for a spontaneous process after taking into account the cell reaction at 25^(@)C . Given : K_(sp)(AgCl)=2.8xx10^(-10), K_(sp)(AgBr)=3.3xx10^(-13)

Match matrix (E_(Ag^(+)//Ag)^(@)=0.8K_(sp)(AgCl)=10^(-10))

The solubility of AgCl in 0.2 M NaCl is [K_(sp) AgCl =1.8 xx 10^(-10)]

For the galvanic cell: Ag|AgCl(s)|KCl(0.2M)||KBr(0.001M)|AgBr(s)|Ag , calculate the EMF generated and assign correct polarity to each electrode for a spontaneous process after taking into account the cell reaction at 25^(@)C . [K_(sp(AgCl)) = 2.8 xx 10^(-10), K_(sp(AgBr)) = 3.3 xx 10^(-13)]

Ag// AgBr(s) , underset(0.1M)(KBr)// underset(0.1M)(KCl), underset((3))(AgCl)//Ag the cell potential is 0.1x volts. What is x ? (Ksp AgBr = 10^(-16), AgCl= 10^(-11))

For the galvanic cell: Ag|AgCI(s)|KCI(0.2M)||KBr(0.001M)|AgBr(s)|Ag , calculate the EMF generated and assign correct polarity to each electrode for a spontaneous process after taking into account the cell reaction at 25^(@)C . [K_(sp(AgCI)) = 2.8 xx 10^(-10), K_(sp(AgBr)) = 3.3 xx 10^(-13)]

For the galvanic cell: Ag|AgCI(s)|KCI(0.2M)||KBr(0.001M)|AgBr(s)|Ag , calculate the EMF generated and assign correct polarity to each electrode for a spontaneous process after taking into account the cell reaction at 25^(@)C . [K_(sp(AgCI)) = 2.8 xx 10^(-10), K_(sp(AgBr)) = 3.3 xx 10^(-13)]