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Out of 1 M glucose and 2 M glucose, whic...

Out of 1 M glucose and 2 M glucose, which one has a higher boiling point why ?
Wha happens when the external pressure applied becomes more than the osmotic pressure of solution ?

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What happens when the external pressure applied becomes more than the osmotic pressure of solution?

(a) Calculate the freezing point of solution when 1.9 g of MgCl_(2) (M = 95 g Mol^(-1) ) was dissolved in 50g of water, assuming MgCl_(2) undergoes complete ionization. ( K_(f) for water = 1.86 K kg mol^(-1) ). (b) (i) Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why? (ii) What happens when the external pressure applied becomes more than the osmotic pressure of solution?

Between 2M glucose solution and 1M glucose solution which one has a lower freezing point ?