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Give the mechanism of preparation of eth...

Give the mechanism of preparation of ethoxy ethane from ethanol.

Text Solution

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StepI: Protonation of alcohol
`CH_(3)-CH_(2)-underset(..)overset(..)(O)-H+H^(+)overset("slow")(to)CH_(3)-CH_(2)-underset(..)overset(H)overset(|)(""^(+)O)-H`
Step II: Attack of nucleophile:

Step III: Removal of proton
`CH_(3)-underset(H)underset(|)(""^(+)O)-CH_(2)-CH_(3)overset("Fast")(to)CH_(3)-CH_(2)-underset("Ethoxyethane")(O)-CH_(2)-CH_(3)-HI`
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Knowledge Check

  • Ethanol is converted into ethoxy ethane

    A
    by treating with conc.`H_2SO_4` at room temperature
    B
    By heating excess of ethanol with conc.`H_2SO_4` at 140@C
    C
    by treating with conc.`H_2SO_4` at 273K
    D
    by heating ethanol with excess of conc.`H_2SO_4` at 443K
  • Ethanol is converted into ethoxy ethane,

    A
    by heating excess of ethanol with conc. `H_2 SO_4` at `140^@ `C
    B
    by heating Ethanol with excess of conc. `H_2 SO_4 `at 443 K.
    C
    by treating with conc `H_2 SO_4` at room temperature.
    D
    by treating with conc `H_2 SO_4` at 273 K.
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