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Effective nuclear charge (Z(eff)) is the...

Effective nuclear charge `(Z_(eff))` is the net attractive force on electrons under consideration and is equal to:
`Z_(eff) = Z - sigma` (nuclear charge - screening constant). `Z_(eff)` or `sigma` is calculated by Slater's formula, as given.
If one electrons is present in the outermst orbit, there will be no screening in that orbital. Each electrons contribute, `0.35` (total electrons minus one electron) present in the outermost shell.
A contribution of `0.85` for each electrons is taken in the `(n - 1)th` shell.
Which of the following statement is wrong?

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Effective nuclear charge (Z_(eff)) is the net attractive force on electrons under consideration and is equal to: Z_(eff) = Z - sigma (nuclear charge - screening constant). Z_(eff) or sigma is calculated by Slater's formula, as given. If one electrons is present in the outermst orbit, there will be no screening in that orbital. Each electrons contribute, 0.35 (total electrons minus one electron) present in the outermost shell. A contribution of 0.85 for each electrons is taken in the (n - 1)th shell. The screening constant (sigma) for 4s electron of Mn (Z = 25) will be

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