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NON-IDEAL SOLUTIONS

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Compreshension-II In non-ideal solutions, at one of the intermediate compostions, the total vapour pressure is highest and the boiling point is lowest. At this point, the composition of the liquid and vapour phase is same. So, if liquid mixture vapouriese at this point and vapours are condensed, the condensate contains same compositon as present in original liquid mixture. it means at this point liquid behaves like a pure liquid and is called an Azeotropic mixture. A and B forms non-ideal solution showing positive deviation. Boiling point of pure A and B is 350 K and 380 K respectively. The solution will bpoil at (approximate)

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When non-ideal solution was prepared by mixing 30 mL chloroform and 50 mL acetone. The volume of mixture will be

100 mL of liquid A was mixed with 25 mL of liquid B to give non-ideal solution of A-B. The volume of this mixture will be