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On the basis of the given equivalent con...

On the basis of the given equivalent conductivity
`lamda_(oo)(NH_(4)Cl)=130`
`lamda_(oo)(OH^(-))=174`
`lamda_(oo)(Cl^(-))=66`
The value of `lamda_(oo)(NH_(4)OH)` will be

A

304

B

238

C

108

D

64

Text Solution

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The correct Answer is:
To find the equivalent conductivity of \( \lambda_{\infty}(NH_4OH) \), we can use the concept of equivalent conductivities of the ions involved in the dissociation of ammonium hydroxide. 1. **Identify the ions in \( NH_4OH \)**: The dissociation of ammonium hydroxide can be represented as: \[ NH_4OH \rightarrow NH_4^+ + OH^- \] Therefore, the ions involved are \( NH_4^+ \) and \( OH^- \). 2. **Use the formula for equivalent conductivity**: The equivalent conductivity of a compound can be calculated using the equivalent conductivities of its constituent ions: \[ \lambda_{\infty}(NH_4OH) = \lambda_{\infty}(NH_4^+) + \lambda_{\infty}(OH^-) \] 3. **Substitute the known values**: From the given data: - \( \lambda_{\infty}(NH_4Cl) = 130 \) - \( \lambda_{\infty}(OH^-) = 174 \) - \( \lambda_{\infty}(Cl^-) = 66 \) We need to find \( \lambda_{\infty}(NH_4^+) \). Since \( NH_4Cl \) dissociates into \( NH_4^+ \) and \( Cl^- \), we can express: \[ \lambda_{\infty}(NH_4^+) = \lambda_{\infty}(NH_4Cl) - \lambda_{\infty}(Cl^-) \] Substituting the values: \[ \lambda_{\infty}(NH_4^+) = 130 - 66 = 64 \] 4. **Calculate \( \lambda_{\infty}(NH_4OH) \)**: Now substitute \( \lambda_{\infty}(NH_4^+) \) and \( \lambda_{\infty}(OH^-) \) into the equation: \[ \lambda_{\infty}(NH_4OH) = \lambda_{\infty}(NH_4^+) + \lambda_{\infty}(OH^-) \] \[ \lambda_{\infty}(NH_4OH) = 64 + 174 = 238 \] 5. **Final Result**: Therefore, the value of \( \lambda_{\infty}(NH_4OH) \) is: \[ \lambda_{\infty}(NH_4OH) = 238 \]

To find the equivalent conductivity of \( \lambda_{\infty}(NH_4OH) \), we can use the concept of equivalent conductivities of the ions involved in the dissociation of ammonium hydroxide. 1. **Identify the ions in \( NH_4OH \)**: The dissociation of ammonium hydroxide can be represented as: \[ NH_4OH \rightarrow NH_4^+ + OH^- \] Therefore, the ions involved are \( NH_4^+ \) and \( OH^- \). ...
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