Home
Class 12
CHEMISTRY
What is the % dissociation of CH(3)COOH,...

What is the % dissociation of `CH_(3)COOH`, if equivalent conductivity at this dilution and at infinite dilution are 148 and 398 S `cm^(2)//mol` respectively

A

`37.18%`

B

`47%`

C

`48.78%`

D

`10.8%`

Text Solution

AI Generated Solution

The correct Answer is:
To find the percentage dissociation of acetic acid (CH₃COOH), we can use the formula relating equivalent conductivity at a given dilution and at infinite dilution. The steps to solve the problem are as follows: ### Step 1: Understand the relationship between equivalent conductivity and dissociation The equivalent conductivity (Λ) of a weak electrolyte can be expressed in terms of its degree of dissociation (α) and its concentration (C). The formula is: \[ \Lambda = \alpha \Lambda_0 \] where: - \( \Lambda \) is the equivalent conductivity at a given dilution (148 S cm²/mol in this case), - \( \Lambda_0 \) is the equivalent conductivity at infinite dilution (398 S cm²/mol). ### Step 2: Set up the equation From the relationship, we can express the degree of dissociation (α) as: \[ \alpha = \frac{\Lambda}{\Lambda_0} \] ### Step 3: Substitute the values Now, substitute the given values into the equation: \[ \alpha = \frac{148}{398} \] ### Step 4: Calculate α Now, perform the division: \[ \alpha = 0.3718 \] ### Step 5: Convert α to percentage To find the percentage dissociation, multiply α by 100: \[ \text{Percentage dissociation} = \alpha \times 100 = 0.3718 \times 100 \] ### Step 6: Final calculation Calculating this gives: \[ \text{Percentage dissociation} = 37.18\% \] Thus, the percentage dissociation of CH₃COOH is approximately **37.18%**.

To find the percentage dissociation of acetic acid (CH₃COOH), we can use the formula relating equivalent conductivity at a given dilution and at infinite dilution. The steps to solve the problem are as follows: ### Step 1: Understand the relationship between equivalent conductivity and dissociation The equivalent conductivity (Λ) of a weak electrolyte can be expressed in terms of its degree of dissociation (α) and its concentration (C). The formula is: \[ \Lambda = \alpha \Lambda_0 \] where: - \( \Lambda \) is the equivalent conductivity at a given dilution (148 S cm²/mol in this case), - \( \Lambda_0 \) is the equivalent conductivity at infinite dilution (398 S cm²/mol). ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ERRORLESS |Exercise Ordinary Thinking Objective Questions (Cell constant and Electrochemical cells)|76 Videos
  • ELECTROCHEMISTRY

    ERRORLESS |Exercise Ordinary Thinking Objective Questions (Corrosion)|6 Videos
  • ELECTROCHEMISTRY

    ERRORLESS |Exercise Ordinary Thinking Objective Questions (Faradays law of electrolysis)|94 Videos
  • D & P-BLOCK ELEMENTS

    ERRORLESS |Exercise JEE Section (Numeric answer type questions)|2 Videos
  • ENVIRONMENTAL CHEMISTRY

    ERRORLESS |Exercise CRITICAL THINKING (Objective question )|16 Videos

Similar Questions

Explore conceptually related problems

The equivalent conductance at infinite dilution of a weak acid such as HF

Calculate molar conductivity at infinite dilution of CH_3COOH if molar conductivity at infinite dilution of CH_3COONa, HCI and MaCI are 91.6, 425.0 and 128.1 S cm^2 "mol"^(-1) .

For the strong electrolytes NaOH, NaCl and BaCl_(2) the molar ionic conductivities at infinite dilution are 250, 125 and 300 "mho cm"^(2)"mol"^(-1) respectively. The molar conductivity of Ba(OH)_(2) at infinite dilution ("mho cm"^(2)"mol"^(-1)) is .

The conductivity of 0.001 M acetic is 4 xx 10^(-5)S//cm. Calculate the dissociation constant of acetic acid, if molar conductivity at infinite dilution for acetic is 390 S cm^(2)//mol.

ERRORLESS -ELECTROCHEMISTRY-Ordinary Thinking Objective Questions (Conductor And conductance)
  1. The equivalent conductance of 1 M benzoic acid is 12.8 ohm^(-1) cm^(2)...

    Text Solution

    |

  2. At 25^(@)C, the molar conductances at infinite dilution for the strong...

    Text Solution

    |

  3. What is the % dissociation of CH(3)COOH, if equivalent conductivity at...

    Text Solution

    |

  4. Electrolytic conduction differs from metallic conduction. In case of m...

    Text Solution

    |

  5. At^(3)Y, minimum numbers of elecrolyte required for a compound to obta...

    Text Solution

    |

  6. Which one is NOT a conductor of electricity ?

    Text Solution

    |

  7. What is the effect of dilution on the equivalent conductance of strong...

    Text Solution

    |

  8. Conductivity (Unit Siemen's 'S') is directly proportional to area of t...

    Text Solution

    |

  9. The highest electrical conductivity of the following aqueous solutions...

    Text Solution

    |

  10. The molar conductivities Lambda(NaOAc)^@ and Lambda(HCI)^@ at infinite...

    Text Solution

    |

  11. Resistance of a conductvity cell filled with a solution of an electrol...

    Text Solution

    |

  12. The equivalent conductances of two strong electrolytes at infinite di...

    Text Solution

    |

  13. The molar conductivities of KCl, NaCl and KNO(3) are 152,128 and 111" ...

    Text Solution

    |

  14. If X is the conductivity of the solution and M is the molarity of the ...

    Text Solution

    |

  15. The unit ohm^(-1) is used for

    Text Solution

    |

  16. The correct expression in SI system relating the equivalent conductanc...

    Text Solution

    |

  17. Assertion:Molar conductivity increases with decrease in concentration....

    Text Solution

    |

  18. The molar conductivity is maximum for the solution of concentration .

    Text Solution

    |

  19. The units of molar conductance are

    Text Solution

    |

  20. Molar conductance of electrolytic solution wedge(m) is

    Text Solution

    |