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Assertion: The cell potential of mercury...

Assertion: The cell potential of mercury cell is 1.35V which remains constant.
Reason: In mercury cell, the electrolyte is a paste of KOH and ZnO.

A

if both assertion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are true but reason is not the correct explanation of the assertion.

C

If assertion is true but reason is false

D

If the assertion and reason both are false.

Text Solution

Verified by Experts

The correct Answer is:
B

`Zn_((s))+Cu_((aq))^(2+)toZn_((aq))^(2+)+Cu_((s))`
As the time passes, the concentration of `Zn^(2+)` keeps on increasing while the concentration of `Cu^(2+)` keeps on decreasing. At the same time voltage of the cell keeps on decreasing. When there is no change in concentration of `Cu^(2+) and Zn^(2+)` ions, voltmeter gives zero reading and this state is known as equilibrium.
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The questions consist of two atatements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses : The cell potential of mercury cell is 1.35 V , which remains constant . In mercury cell, the electrolute is a paste of KOH and ZnO.

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