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The cell reaction of the galvanic cell :...

The cell reaction of the galvanic cell : `Cu_((s))|Cu_((aq))^(2+) ||Hg_((aq))^(2+) |Hg_((l))` is

A

`Hg+Cu^(2+)toHg^(2+)+Cu`

B

`Hg+Cu^(2+)toCu^(2+)+Hg^(+)`

C

`Cu+HgtoCuHg`

D

`Cu+Hg^(2+)toCu^(2+)+Hg`

Text Solution

Verified by Experts

The correct Answer is:
d

`underset("anode oxidation")(Cu_((s))|Cu_((ag))^(2+))||underset("cathode reduction")(Hg_((Ag))^(2+)|Hg_((l)))`
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The cell reaction of the galvanic cell: Cu(s)|Cu^(2+)(aq)||Hg^(2+)(aq)|Hg(l) is

For the Daniel Cell involving the cell reaction Zn_((s))+Cu_((aq))^(+2)hArrZn_((aq))^(+2)+Cu_((s)) the standard free energies of formation of Zn_((s)),Cu_((s)),Cu_((aq))^(+2) and Zn_((aq))^(+2) are 0, 0, 64.4 KJ/Mole and -154.0 KJ/Mole, respectively. Calculate the standard EMF of the cell