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Consider the reaction M((aq))^(n+)+n e^(...

Consider the reaction `M_((aq))^(n+)+n e^(-)toM_((s))`. The standard reduction potential values of the element `M_(1),M_(2) and M_(3)` are -0.34V,-3.05 and -1.66V respectively. The order of their reducing power will be:-

A

`M_(1) gt M_(2) gt M_(3)`

B

`M_(3) gt M_(2) gt M_(1)`

C

`M_(1) gt M_(3) gt M_(2)`

D

`M_(2) gt M_(3) gt M_(1)`

Text Solution

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The correct Answer is:
To determine the order of reducing power for the elements \( M_1, M_2, \) and \( M_3 \) based on their standard reduction potentials, we can follow these steps: ### Step 1: Write down the standard reduction potentials The standard reduction potentials for the elements are given as follows: - \( E^\circ(M_1) = -0.34 \, \text{V} \) - \( E^\circ(M_2) = -3.05 \, \text{V} \) - \( E^\circ(M_3) = -1.66 \, \text{V} \) ### Step 2: Understand the relationship between reduction potential and reducing power The reducing power of a species is inversely related to its standard reduction potential. A more negative reduction potential indicates a stronger reducing agent. Thus, the order of reducing power can be determined by comparing the values of the standard reduction potentials. ### Step 3: Compare the standard reduction potentials - The most negative potential is \( -3.05 \, \text{V} \) for \( M_2 \). - The next most negative is \( -1.66 \, \text{V} \) for \( M_3 \). - The least negative is \( -0.34 \, \text{V} \) for \( M_1 \). ### Step 4: Determine the order of reducing power Based on the comparison: - \( M_2 \) has the highest reducing power (most negative potential). - \( M_3 \) has a moderate reducing power. - \( M_1 \) has the lowest reducing power (least negative potential). Thus, the order of reducing power is: \[ M_2 > M_3 > M_1 \] ### Final Answer The order of reducing power is \( M_2 > M_3 > M_1 \). ---

To determine the order of reducing power for the elements \( M_1, M_2, \) and \( M_3 \) based on their standard reduction potentials, we can follow these steps: ### Step 1: Write down the standard reduction potentials The standard reduction potentials for the elements are given as follows: - \( E^\circ(M_1) = -0.34 \, \text{V} \) - \( E^\circ(M_2) = -3.05 \, \text{V} \) - \( E^\circ(M_3) = -1.66 \, \text{V} \) ...
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