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The standard electrode potentials (E^(@)...

The standard electrode potentials `(E^(@)) " for " Ocl^(-)//Cl^(-) " and " Cl^(-)//(1)/(2) Cl_(2)` respectively are 0.94 V and `-1.36 V`. The `E^(@)` value for `Ocl^(-)// (1)/(2) Cl^(2)` will be:

A

`-0.42V`

B

`-2.20V`

C

`0.52V`

D

`1.04V`

Text Solution

Verified by Experts

The correct Answer is:
C

`OC l^(-)toCl^(-),E^(o)=0.94V`
`Cl^(-)to(1)/(2)Cl_(2)+e^(-)E^(o)=-1.36V`
adding the two equations, we get
`OC l^(-)to(1)/(2)Cl_(2),E^(o)=0.94-1.36=-0.42V`.
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