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In the reaction of sodium thiosulphate w...

In the reaction of sodium thiosulphate with `I_(2)` in aqueous medium, the equivalent mass of sodium sulphate

A

Molar mass of sodium thisosulphate

B

The average of molar masses of `Na_(2)S_(2)O_(3)` and `I_(2)`

C

Half the molar mass of sodium thiosulphate

D

Molar mass of sodium thiosulphate `xx2`

Text Solution

Verified by Experts

The correct Answer is:
A

`2 Na_(2)S_(2)O_(3).5H_(2)O+I_(2) rarr 2NaI+Na_(2)S_(4)O_(6)`
or `2 S_(2)O_(3)^(2-) rarr S_(4)O_(6)^(2-)+2e^(-)`
Equivalent weight of `Na_(2)S_(2)O_(3).5H_(2)O`
`=("Mol. wt.")/1=248/1=248`.
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