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Equivalent weight of KMnO(4) acting as a...

Equivalent weight of `KMnO_(4)` acting as an oxidant in acidic medium is

A

The same as its molecular weight

B

Half of its molecular weight

C

One-third of its molecular weight

D

One-fifth of its molecular weight

Text Solution

Verified by Experts

The correct Answer is:
D


Eq. wt. `=("Mol. Wt.")/5`
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The equivalent weight of KMnO_(4) in (a) neutral medium, (b) acidic medium and (c ) alkaline medium is M//.. ( where M is mol.wt. of KMnO_(4) )

The equivalent weight of KMnO_4 in a redox reaction in a neutral medium is .

KMnO_(4) reacts with KI in acidic medium gives

A : Equivalent weight of KMnO_(4) in acidic medium is M/5 . R : In acidic medium 1 mol of MnO_(4)""^(-) gains 5 electron.

STATEMENT-1 KMnO_(4) acts as powerful oxidising agent in acids, alkaline and neutral medium. STATEMENT-2: Equivalent weight of KMnO_(4) in acidic medium in M/5 and in strongly alkaline medium in M/3. STATEMENT-3 : KMnO_(4) solution is used as a primary standard and acts as self indicator during its titration more Mohr salt.

Assertion :- Equivalent weight of KMnO_(4) in acidic medium is M//5 (M=molecular weight) while in basic medium, it is equal of M/3. Reason :- In acidic medium, 1 mol of MnO_(4)^(-) gains 5 mole electrons while in basic medium it gains 3 mole electrons.

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