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Which is smaller, terminal-p.d. or e.m.f...

Which is smaller, terminal-p.d. or e.m.f. of a cell and why ?

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A potentiometer wire is 10 m long and a P.D. of 6 V is maintained between its ends. The e.m.f. of the cell which balances against a length of 200 cm of the potentiometer wire is