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Explain the variations in the following ...

Explain the variations in the following properties of group-18 elements :
(i) Atomic radii
(ii) Ionisation enthalpy
(iii) Electron gain enthalpy

Text Solution

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(i) Atomic radii: The atomic radii of noble gases in their respective periods are exceptionally high because incase of noble gases, the atomic radii corresponds to Van-der-Waal.s radii which is always larger than covalent radii.
Down the group, the atomic radii increases with the increase in atomic number.
(ii) Ionisation enthalpy : Ionisation enthalpies of noble gases are exceptionally high due to presence of fully filled valence shells. However down the group the ionisation enthalpy decreases.
(iii) Electron gain enthalpy : The values of electron gain enthalpies are large positive as they have fully filled valance shells. Hence, they have no tendency to accept electrons and form anions
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