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Which of the following reacts with AsF(3...

Which of the following reacts with `AsF_(3)` in liquid `BrF_(3)`?

A

`XeF_(6)` only

B

`XeF_(6)` and `XeF_(4)`

C

`XeF_(2)` and `XeF_(6)`

D

`XeF_(6)` and `XeF_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`XeF_6` and `XeF_2` is a `F^(-)` donor. It reacts with `PF_5, AsF_5` and `SbF_5` in presence of covalent solvent such as `BrF_3`.
`XeF_(2) + 2AsF_(5) to [XeF]^(+) + [As_(2)F_(11)]^(-)`
`XeF_(6) + AsF_(5) to [XeF]^(+) + [AsF_(6)]^(-)`
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