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The equivalent mass of K(2)Cr(2)O(7) whe...

The equivalent mass of `K_(2)Cr_(2)O_(7)` when it acts as oxidising agent in acidic medium, is equal to 

A

M/3

B

M/2

C

M/6

D

M/5

Text Solution

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The correct Answer is:
C
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(A): Equivalent mass of K_(2)Cr_(2)O_(7) , when it acts as oxidizing agent in acidic medium, is M/3 (R) : During reduction, oxidation number of chromium changes from +6 to +3

Equivalent weights of K_(2)Cr_(2)O_(7) in acidic medium is

The equivalent weights of oxidising and reducing agents can be calculated by the number of electrons gained or lost. The equivalent weight of an oxidising agent is the number of parts by weight of the substance which gains one electron. Thus, it is equal to the molecular weight of the substance divided by the number of electrons gained in the balanced chemical equation. Similarly, equivalent weight of a reducing agent is equal to the molecular weight divided by the number of electrons lost as represented in the balanced chemical equation The equivalent weight of barium in BaCrO_4 used as an oxidising agent in acidic medium is (At, wt, of Ba - 137.34)

Equivalent weight of K_(2)Cr_(2)O_(7) as oxidant in acidic medium is

(A) Equivalent mass of KMnO_4 is equal to one-third of its molecular mass when it acts as an oxidising agent in faint alkaline medium (R) Oxidation number of Mn is +7 KMnO_4

The atomicity of K_2Cr_2O_7 is

In which of the following reactions, H_(2)O_(2) acts as oxidising agent ?

Acidified K_(2)Cr_(2)O_(7) turns green by

Why does O_(3) act as a powerful oxidising agent ?

AAKASH SERIES-D - BLOCK ELEMENTS-PRACTICE EXERCISE
  1. As the oxidation state of metal in metal oxide increases its acidic na...

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  2. Highest oxidation state exhibited by a lanthanide element is

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  3. Lanthanides are rare earths, but one of them is not available naturall...

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  4. The element with highest number of unpaired L electrons is

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  5. Colour exhibited by divalent Sm in aqueous solutions

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  6. Which of the following is paramagnetic ?

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  7. Compound that is both paramagnetic and coloured is

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  8. Acidic oxide is formed by the metal and oxidation state of the metal i...

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  9. In the preparation of KMnO4, pyrolusite (MnO(2)) is first converted to...

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  10. Which of the following can be employed for the conversion of potassium...

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  11. The reaction MnO(4)^(-)+e^(-)hArrMnO(4)^(2) takes place in

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  12. When MnO(2) is fused with KOH in the presence of air, a coloured compo...

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  13. Acidified potassium dichromate is treated with hydrogen sulphide. In t...

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  14. The equivalent mass of K(2)Cr(2)O(7) when it acts as oxidising agent i...

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  15. The aqueous solution containing which one of the following ion will be...

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  16. Effective magnetic moment of Sc^(3+) ion is

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  17. The stable oxiation state of Cu, Ag and Au are respectively

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  18. Highest oxidation state exhibited by a lanthanide element is

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  19. Larger number of oxidation states are exhibited by the actinoids than ...

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  20. Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because

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