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Components of a binary mixture of two li...

Components of a binary mixture of two liquids A and B were being separated by distillation. After some time separation of components stopped and composition of vapour phase became same as that of liquid phase. Both the components started coming in the distillate. Explain why this happened.

Text Solution

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Since both the components are appearing in the distillate and composition of liquid and vapour is same, this shows that liquids have formed azeotropic mixture and hence cannot be separated at this stage by fractional distillation.
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Knowledge Check

  • Assertion (A): Components of a mixture of red and blue inks can be separated by distributing the components between stationary and mobile phases in paper chromatography. Reason ( R): The coloured components of inks migrate at different rates because paper selectively retains different components according to the difference in their partition between the two phases

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    B
    Both (A) and R are correct but (R ) is not the correct explanation of (A)
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    Both (A) and (R ) are not correct
    D
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    A
    Both (A ) and (R ) are correct and (R ) is the correct explanation of (A)
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  • Which of the following binary mixtures will have same composition in liquid and vapour phase ?

    A
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