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Assertion : When methyl alcohol is added...

Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.

A

Assertion and reason both are correct statements and reason is correct explanation for assertion.

B

Assertion and reason both are correct statements but reason is not correct explanation for assertion.

C

Assertion is correct statement but reason is wrong statement.

D

Assertion and reason both are incorrect statements.

Text Solution

Verified by Experts

The correct Answer is:
D

Explanation : (A) Methyl alcohol & water both are volatile liquids which when mixed together to form a binary solution, the vapour pressure of this solution becomes more as compared to individual pure components. This affects the boiling point of water with a decrease. Further,
(B) When methyl alcohol is added to water A-B interaction `lt` A-A or B-B interaction that is why it will show positive deviation from Raoult.s law. Since a positive deviation from Rault.s law indicates a rise in vapour pressure the boiling point decreases.
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