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Explain the factors favouring S(N)2 reac...

Explain the factors favouring `S_(N)2` reaction.

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The `S_(N)2` reaction requires the approach of the nuclephile to the carbon bearing the leaving group, and the presence of bulky substituents on or near the carbon atom retards the attack of nuclephile. Thus, the methyl halides react more rapidly in `S_(N)2` reactions because there are only three small hydrogen atoms.
Tertiary halides are the least reactive because bulky groups hinder the approach of nucleophiles. Thus, order of reactivity is

The `S_(N)2` reaction is also favoured by strong nucleophiles and polar aprotic solvents such as acetone, dimethylsulpoxide (DMSO) etc. Also the presence of strong electron withdrawing group favours `S_(N)2`.
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The order of reactivities of the following alky halides for an S_(N)2 reaction is .

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KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - A QUESTIONS
  1. Write a note on nucleophiles.

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  2. Write a note on S(N)2 mechanism.

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  3. Explain the factors favouring S(N)2 reaction.

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  4. Write a note on S(N)1 reaction.

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  5. Explain the factors affecting S(N)1 reaction.

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  6. Enlist the main points of difference between S(N)1 and S(N)2 reactions...

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  7. What is retention and inversion of configuration ? Explain with suitab...

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  8. Explain stereochemistry of S(N)1 reaction with suitable example.

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  9. Explain stereochemistry of S(N)2 reaction with suitable example.

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  10. Explain Elimination reactions of alkyl halides.

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  11. Explain dehydrohalogenation (beta - elimination) of alkyl halides.

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  12. Explain how sustitution and elimination reactions compete in the same ...

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  13. Write a note on Grignard Reagent.

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  14. Write a note on Wurtz Reaction.

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  15. Explain why aryl halides are extermely less reactive towards nucleophi...

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  16. Give the reaction of hydroxyl group with chlorobenzene.

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  17. Explain why the electron withdrawing groups such as -NO(2) show its ef...

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  18. Why aryl halides undergo electrophilic substitution reactions at o - a...

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  19. Give following reaction of aryl halides : (i) Halogenation (ii...

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  20. Give reactions of aryl halides with metals.

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