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Explain dehydrohalogenation (beta - elim...

Explain dehydrohalogenation (`beta` - elimination) of alkyl halides.

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When a haloalkane with `beta` - hydrogen atom is heated with alcoholic solution of potassium hydroxide, there is elimination of hydrogen atom from `beta` - carbon and a halogen atom from the `alpha` - carbon atom. As a result, an alkene is formed as a product.
Since `beta` - hydrogen atom is formed as a product.
Since `beta` - hydrogen atom is involved in elimination, it is often called `beta` - elimination.
If there is possibility of formation of more than one alkene due to the availability of more than one `beta` - hydrogen atoms, usually one alkene is formed as the major product.

These form part of a pattern first observed by Russian chemist, ..Alexander Zaitsev... He formulated rule which can be summarised as :
..In dehydrohalogenation reactions, the preferred product is that alkene which has greater number of alkyl groups attached to doubly bonded carbon atoms... Thus, 2-bromopentane gives pent-2-ene as the major product.
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KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - A QUESTIONS
  1. Explain stereochemistry of S(N)1 reaction with suitable example.

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  2. Explain stereochemistry of S(N)2 reaction with suitable example.

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  3. Explain Elimination reactions of alkyl halides.

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  4. Explain dehydrohalogenation (beta - elimination) of alkyl halides.

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  5. Explain how sustitution and elimination reactions compete in the same ...

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  6. Write a note on Grignard Reagent.

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  7. Write a note on Wurtz Reaction.

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  8. Explain why aryl halides are extermely less reactive towards nucleophi...

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  9. Give the reaction of hydroxyl group with chlorobenzene.

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  10. Explain why the electron withdrawing groups such as -NO(2) show its ef...

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  11. Why aryl halides undergo electrophilic substitution reactions at o - a...

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  12. Give following reaction of aryl halides : (i) Halogenation (ii...

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  13. Give reactions of aryl halides with metals.

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  14. State the various uses of : Dichloromethane (Methylene chloride)

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  15. State the various uses of : Trichloromethone (Chloroform)

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  16. State the various uses of : Tri - iodomethane (Iodoform)

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  17. State the various uses of : Tetrachloromethane (Carbon tetrachlorid...

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  18. State the various uses of : Freons

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  19. State the adverse effects of polyhalogenated compounds. How the advers...

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  20. Write a note on DDT.

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