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The order of reactivity of following alc...

The order of reactivity of following alcohols with halogen acids is ………
(A) `CH_(3)CH_(2)-CH_(2)-OH`
(B) `CH_(3)CH_(2)-underset(CH_(3))underset("| ")("C ")H-OH`
(C ) `CH_(3)CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")("C ")-OH`

A

`(A)gt (B)gt (C )`

B

`(C )gt (B)gt (A)`

C

`(B)gt (A)gt (C )`

D

`(A)gt (C )gt (B)`

Text Solution

Verified by Experts

The correct Answer is:
B

The reaction of halogen acids with alcohol procceeds through carbocation intermediate. Greater stability of Carbocation, faster is the reaction. The stability order is `3^(@)gt 2^(@)gt 1^(@)`.
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Knowledge Check

  • H_(3)C-underset(CH_(3))underset("| ")("C ")H-CH=CH_(2)overset(HBr)rarr

    A
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    B
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    C
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    D
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  • Which monomer is present in CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C " polymer ?

    A
    B
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    C
    `CH_(3)-CH=CH_(2)`
    D
    `(CH_(3))_(2)C=C-(CH_(3))_(2)`
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    A
    `CH_(3)-CH=CH-CH_(3)`
    B
    `CH_(2)=CH-CH_(2)CH_(3)`
    C
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