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Ethylene chloride and ethylidene chlorid...

Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.

A

Both the compounds form same product on treatment with alcoholic KOH.

B

Both the compounds form same product on treatment with aq. NaOH.

C

Both the compounds form same product on reduction.

D

Both the compounds are optically active.

Text Solution

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The correct Answer is:
A, C

`underset("Ethylene dichloride")(H_(2)underset("Cl ")underset("| ")("C ")-underset("Cl ")underset("| ")("C ")H_(2))overset(" 2KOH ")underset(" Ethanol ")rarr underset("Ethyne")(HC-=CH)`
`underset("Ethylidine chloride")(H_(3)C-overset("Cl ")overset("| ")underset("Cl ")underset("| ")("C ")H)overset(" 2KOH ")underset(" Ethanol ")rarr underset("Ethyne")(HC-=CH)`
`CH_(3)CHCl_(2)overset(" Zn ")underset(" Ethanol ")rarr H_(2)C=CH_(2)`
`Cl-CH_(2)-CH_(2)-Cl overset(" Zn ")underset(" Ethanol ")rarr CH_(2)=CH_(2)`
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